Table A1. Best values, from instrumental neutron activation analysis.
|
AGV-1 |
ATT-1 |
BCR-1 |
BHVO-1 |
BIR-1 |
BSK-1 |
CSB-1 |
DNC-1 |
DTS-1* |
G-2 |
||
|
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
||
|
Na |
% |
3.16 |
0.0455 |
2.44 |
1.689 |
1.355 |
2.85 |
1.74 |
1.445 |
0.0053 |
3.06 |
|
K |
% |
2.3 |
0.65 |
n.a. |
n.a. |
<1. |
2.3 |
(0.44) |
n.a. |
n.a. |
3.7 |
|
Ca |
% |
3.53 |
1.22 |
5.08 |
8.42 |
9.4 |
2.85 |
0.90 |
8.0 |
<0.5 |
1.39 |
|
Sc |
µg/g |
11.80 |
8.69 |
32.1 |
31.2 |
43.7 |
6.87 |
5.20 |
31.4 |
3.38 |
3.35 |
|
Cr |
µg/g |
8.73 |
134. |
10.8 |
294. |
408. |
51. |
<3. |
296. |
4250. |
7.3 |
|
Fe |
% |
4.68 |
2.11 |
9.34 |
8.64 |
7.99 |
2.04 |
2.41 |
6.99 |
6.00 |
1.85 |
|
Co |
µg/g |
15.39 |
5.74 |
37.2 |
45.4 |
53.6 |
7.55 |
0.666 |
58.3 |
138.4 |
4.44 |
|
Ni |
µg/g |
(14.) |
21. |
<50 |
125. |
178. |
30. |
<25. |
281. |
2400. |
<12 |
|
Zn |
µg/g |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
As |
µg/g |
0.89 |
2.90 |
0.61 |
0.54 |
<1. |
2.7 |
2.74 |
<1. |
<1. |
(0.24) |
|
Se |
µg/g |
<1. |
<0.4 |
<1. |
<1. |
<2. |
5.4 |
(0.22) |
<1. |
<1. |
<0.3 |
|
Br |
µg/g |
(0.19) |
0.62 |
<0.4 |
0.22 |
<2. |
17.3 |
(0.19) |
<0.5 |
<1. |
<0.5 |
|
Rb |
µg/g |
67.6 |
48.5 |
49.1 |
10.1 |
<10. |
101. |
10.4 |
4.9 |
<5. |
168. |
|
Sr |
µg/g |
659. |
70. |
336. |
407. |
114. |
400. |
211. |
151. |
<10. |
482. |
|
Y |
µg/g |
[18.9] |
[23.] |
[36.] |
[27.] |
[16.2] |
[15.6] |
[46.] |
[17.5.] |
n.a. |
[10.7] |
|
Zr |
µg/g |
219. |
192. |
177. |
165. |
<100. |
152. |
186. |
(46.) |
<40. |
327. |
|
Ag |
µg/g |
n.a. |
(0.18) |
n.a. |
n.a. |
n.a. |
<1. |
0.22 |
n.a. |
n.a. |
<0.5 |
|
Cd |
µg/g |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
Sb |
µg/g |
4.2h |
2.65 |
0.59 |
0.149 |
0.47 |
<0.86>H |
2.38 |
0.81 |
<0.60>H |
0.045 |
|
Cs |
µg/g |
1.29 |
2.83 |
0.957 |
0.098 |
<0.3 |
3.17 |
0.164 |
0.220 |
<0.05 |
1.34 |
|
Ba |
µg/g |
1194. |
141. |
661. |
126. |
<40. |
769. |
345. |
103. |
<40. |
1854. |
|
La |
µg/g |
38.6 |
23.9 |
25.1 |
15.51 |
0.601 |
23.2 |
56.3 |
3.70 |
<0.06 |
89.3 |
|
Ce |
µg/g |
68.9 |
42.1 |
52.6 |
37.8 |
2.03 |
45.5 |
120.2 |
8.26 |
n.a. |
164. |
|
Pr |
µg/g |
[7.8] |
[5.0] |
[6.5] |
[5.1] |
[0.4] |
[4.9] |
[13.] |
[1.0] |
n.a. |
[16.] |
|
Nd |
µg/g |
31.3 |
20.7 |
27.5 |
23.5 |
<10. |
17.9 |
49. |
4.5 |
<1. |
52.0 |
|
Sm |
µg/g |
5.89 |
4.32 |
6.65 |
6.23 |
1.097 |
3.55 |
10.97 |
1.44 |
<0.015 |
7.33 |
|
Eu |
µg/g |
1.602 |
0.847 |
1.942 |
2.08 |
0.518 |
0.819 |
0.703 |
0.590 |
<0.02 |
1.34 |
|
Gd |
µg/g |
[4.4] |
[3.7] |
[6.2] |
[6.3] |
[1.9] |
[2.7] |
[8.9] |
[2.0] |
n.a. |
[3.7] |
|
Tb |
µg/g |
0.644 |
0.619 |
1.03 |
0.947 |
0.366 |
0.431 |
1.39 |
0.382 |
<0.1 |
0.449 |
|
Dy |
µg/g |
[3.6] |
[3.9] |
[6.3] |
[5.4] |
[2.5] |
[2.6] |
[8.3] |
[2.6] |
n.a. |
[2.3] |
|
Ho |
µg/g |
[0.71] |
[0.85] |
[1.3] |
[1.05] |
[0.58] |
[0.57] |
[1.7] |
[0.62] |
n.a. |
[0.42] |
|
Er |
µg/g |
[1.8] |
[2.3] |
[3.6] |
[2.6] |
[1.6] |
[1.6] |
[4.5] |
[1.8] |
n.a. |
[0.99] |
|
Tm |
µg/g |
[0.26] |
[0.35] |
[0.52] |
[0.34] |
[0.25] |
[0.23] |
[0.63] |
[0.28] |
n.a. |
[0.13] |
|
Yb |
µg/g |
1.63 |
2.27 |
3.30 |
1.967 |
1.66 |
1.51 |
3.84 |
1.94 |
<0.1 |
0.720 |
|
Lu |
µg/g |
0.244 |
0.339 |
0.487 |
0.268 |
0.246 |
0.234 |
0.52 |
0.296 |
<0.01 |
0.0997 |
|
Hf |
µg/g |
5.31 |
5.44 |
5.00 |
4.56 |
0.60 |
4.31 |
8.74 |
1.04 |
<0.05 |
8.2 |
|
Ta |
µg/g |
0.833 |
0.57h |
0.757 |
1.161 |
0.038 |
0.719 |
3.46 |
0.085 |
<0.05 |
0.791 |
|
W |
µg/g |
<3. |
<1. |
<2. |
<2. |
<3. |
(1.2) |
<1.5 |
<2 |
<1. |
<2. |
|
Ir |
ng/g |
n.a. |
<2. |
n.a. |
n.a. |
n.a. |
n.a. |
<1. |
n.a. |
n.a. |
<1. |
|
Au |
ng/g |
<5. |
<1.7>H |
<5. |
n.a. |
n.a. |
<3. |
<3. |
< 8. |
n.a. |
(3.) |
|
Hg |
µg/g |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
Th |
µg/g |
6.10 |
6.95 |
5.69 |
1.16 |
<0.1 |
10.4 |
45.3 |
0.210 |
<0.1 |
23.9 |
|
U |
µg/g |
1.98 |
4.73 |
1.66h |
0.41 |
<0.3 |
2.84 |
15.5 |
(0.06) |
<0.2 |
1.92 |
|
LOD |
% |
1.00 |
8.3 |
0.73 |
0.06 |
0.04 |
1.53 |
n.a. |
0.26 |
0.07 |
0.13 |
|
n |
8 |
6 |
9 |
19 |
11 |
5 |
6 |
8 |
15 |
6 |
|
|
mt |
g |
2.04 |
0.61 |
2.00 |
4.20 |
2.10 |
1.17 |
1.03 |
1.63 |
2.63 |
1.04 |
* Updated slightly from reference (4).
Table A1, continued.
|
GSM-1 |
GSP-1 |
GXR-1 |
MAG-1 |
PCC-1 |
QLO-1 |
RGM-1 |
SCo-1 |
SDC-1 |
SDO-1 |
||
|
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
USGS |
||
|
Na |
% |
1.40 |
2.07 |
0.051 |
2.88 |
0.0058 |
3.13 |
3.05 |
0.671 |
1.521 |
0.274 |
|
K |
% |
<1. |
4.8 |
<0.5 |
(3.0) |
n.a. |
2.8 |
3.3 |
2.2 |
n.a. |
2.8 |
|
Ca |
% |
9.2 |
1.36 |
(1.0) |
0.96 |
0.38 |
2.3 |
0.83 |
1.94 |
1.01 |
0.83 |
|
Sc |
µg/g |
38.7 |
5.91 |
1.46 |
16.68 |
8.18 |
8.44 |
4.41 |
11.57 |
14.99 |
12.89 |
|
Cr |
µg/g |
6.4 |
10.4 |
10.4 |
99.4 |
2870. |
1.5 |
2.8 |
70.2 |
62.1 |
65.5 |
|
Fe |
% |
9.31 |
2.97 |
25.1 |
4.79 |
5.73 |
2.99 |
1.28 |
3.54 |
4.80 |
6.48 |
|
Co |
µg/g |
41.5 |
6.68 |
7.8 |
21.5 |
115. |
7.29 |
1.95 |
11.13 |
17.76 |
46.3 |
|
Ni |
µg/g |
<80. |
<30. |
(40.) |
56. |
2400. |
<30. |
<20. |
24. |
38. |
96. |
|
Zn |
µg/g |
n.a. |
n.a. |
800. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
As |
µg/g |
2.4 |
<1. |
438. |
9.6h |
<0.4 |
2.6H |
3.21 |
12.5 |
<0.8 |
69.7 |
|
Se |
µg/g |
<1. |
<0.5 |
18. |
1.11 |
<1. |
<0.5 |
<0.5 |
0.82 |
<0.5 |
1.72 |
|
Br |
µg/g |
<1.2 |
(0.4) |
<2. |
233. |
0.35 |
1.08 |
1.90 |
0.59 |
<0.5 |
3.8 |
|
Rb |
µg/g |
7.5 |
252. |
(10.) |
148. |
<5. |
71.8 |
149. |
111.5 |
124.0 |
125.9 |
|
Sr |
µg/g |
411. |
244. |
330. |
145. |
<20. |
342. |
107. |
175. |
186. |
83. |
|
Y |
µg/g |
[10.1] |
[25.] |
[26.] |
[29.] |
n.a. |
[24.] |
[24.] |
[24.] |
[42] |
[39.] |
|
Zr |
µg/g |
<100. |
610. |
<150. |
132. |
<50. |
182. |
223. |
166. |
317. |
143. |
|
Ag |
µg/g |
<2. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
Cd |
µg/g |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
Sb |
µg/g |
1.75 |
3.14 |
120. |
0.889 |
1.30 |
1.81h |
1.20 |
2.37 |
0.49h |
4.42 |
|
Cs |
µg/g |
0.85 |
1.008 |
2.7 |
8.58 |
<0.1 |
1.68 |
9.93 |
7.77 |
4.00 |
6.65 |
|
Ba |
µg/g |
81. |
1270. |
770. |
471. |
<30. |
1375. |
814. |
559. |
622. |
377. |
|
La |
µg/g |
2.07 |
182. |
7.55 |
41.8 |
0.027 |
26.7 |
23.1 |
29.3 |
42.1 |
36.9 |
|
Ce |
µg/g |
4.99 |
435. |
14.9 |
85.9 |
n.a. |
50.8 |
46.2 |
56.7 |
89.9 |
75.4 |
|
Pr |
µg/g |
n.a. |
[52.] |
[2.0] |
[9.6] |
n.a. |
[5.7] |
[5.0] |
[6.4] |
[10.] |
[8.7] |
|
Nd |
µg/g |
(4.) |
199. |
(10.) |
36.3 |
<2. |
22.4 |
18.3 |
25.4 |
39.4 |
34.4 |
|
Sm |
µg/g |
1.23 |
26.2 |
3.10 |
7.37 |
(0.005) |
4.68 |
4.06 |
5.14 |
8.29 |
7.99 |
|
Eu |
µg/g |
0.550 |
2.21 |
0.64 |
1.42 |
<0.03 |
1.267 |
0.598 |
1.088 |
1.588 |
1.608 |
|
Gd |
µg/g |
[1.6] |
[11.] |
[4.2] |
[5.8] |
n.a. |
[3.9] |
[3.4] |
[4.2] |
[6.6] |
[7.1] |
|
Tb |
µg/g |
0.272 |
1.29 |
0.79 |
0.91 |
<0.03 |
0.644 |
0.591 |
0.675 |
1.10 |
1.152 |
|
Dy |
µg/g |
[1.7] |
[6.0] |
[4.8] |
[5.3] |
n.a. |
[4.0] |
[3.8] |
[4.1] |
[6.9] |
[7.0] |
|
Ho |
µg/g |
[0.37] |
[1.0] |
[0.99] |
[1.1] |
n.a. |
[0.88] |
[0.85] |
[0.89] |
[1.5] |
[1.45] |
|
Er |
µg/g |
[1.0] |
[2.2] |
[2.6] |
[2.9] |
n.a. |
[2.4] |
[2.4] |
[2.4] |
[4.3] |
[3.8] |
|
Tm |
µg/g |
[0.15] |
[0.28] |
[0.36] |
[0.40] |
n.a. |
[0.36] |
[0.37] |
[0.35] |
[0.64] |
[0.55] |
|
Yb |
µg/g |
0.943 |
1.65 |
2.27 |
2.52 |
(0.025) |
2.42 |
2.49 |
2.27 |
4.26 |
3.46 |
|
Lu |
µg/g |
0.142 |
0.230 |
0.35 |
0.376 |
(0.0056) |
0.373 |
0.384 |
0.341 |
0.631 |
0.507 |
|
Hf |
µg/g |
0.84 |
16.1 |
0.77 |
3.66 |
<0.05 |
4.80 |
6.16 |
4.75 |
8.67 |
4.71 |
|
Ta |
µg/g |
0.067 |
0.85 |
(0.10) |
1.083 |
<0.07 |
0.788 |
0.893 |
0.804 |
1.192 |
0.915 |
|
W |
µg/g |
<3. |
<4. |
184. |
(1.5) |
<1. |
(0.5) |
1.5 |
1.5 |
(0.7) |
1.2 |
|
Ir |
ng/g |
n.a. |
<2. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
<2. |
|
Au |
ng/g |
(2.) |
<5. |
4200. H |
n.a. |
n.a. |
n.a. |
n.a. |
2.4 |
n.a. |
2.8 |
|
Hg |
µg/g |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
Th |
µg/g |
0.48h |
102.7 |
2.44 |
11.48 |
<0.04 |
4.55 |
14.07 |
9.01 |
11.32 |
9.58 |
|
U |
µg/g |
(0.17) |
2.37 |
35. |
2.45 |
<0.2 |
1.88 |
5.74 |
3.00 |
3.0h |
47.9 |
|
LOD |
% |
0.12 |
0.06 |
n.a. |
3.1 |
0.48 |
0.32 |
0.39 |
2.75 |
0.13 |
1.38 |
|
n |
5 |
5 |
3 |
8 |
5 |
7 |
8 |
15 |
7 |
6 |
|
|
mt |
g |
0.81 |
1.22 |
0.29 |
1.54 |
1.29 |
1.36 |
1.57 |
3.31 |
1.44 |
0.90 |
Table A1, continued.
|
SGR-1 |
STM-1 |
TLM-1 |
W-2 |
1c |
69b |
70a |
99a |
278 |
679 |
||
|
USGS |
USGS |
USGS |
USGS |
NIST |
NIST |
NIST |
NIST |
NIST |
NIST |
||
|
Na |
% |
2.25 |
6.66 |
2.21 |
1.67 |
0.0188 |
0.020 |
1.85 |
4.62 |
3.56 |
0.128 |
|
K |
% |
1.24 |
n.a. |
1.31 |
n.a. |
0.24 |
<0.8 |
9.9 |
4.3 |
3.4 |
n.a. |
|
Ca |
% |
5.82 |
0.80 |
4.82 |
7.9 |
35.8 |
<0.6 |
(0.08) |
1.49 |
0.69 |
(0.24) |
|
Sc |
µg/g |
4.94 |
0.522 |
21.8 |
35.6 |
1.203 |
8.32 |
0.088 |
0.208 |
4.98 |
22.8 |
|
Cr |
µg/g |
31.2 |
2.1 H |
14.3 |
92.5 |
17.4 |
73. |
(0.33) H |
0.37 H |
5.7H |
106.7 |
|
Fe |
% |
2.028 |
3.63 |
5.22 |
7.57 |
0.385 |
4.82 |
0.0527 |
0.0411 |
1.413 |
9.05 |
|
Co |
µg/g |
11.73 |
0.72h |
19.4 |
44.7 |
1.079 |
0.96 |
0.0259 |
0.049 |
1.446 |
25.7 |
|
Ni |
µg/g |
26. |
<30. |
<50. |
80. |
7.7 |
<60 |
<8. |
<8. |
<25. |
55. |
|
Zn |
µg/g |
n.a. |
242. |
n.a. |
n.a. |
29. |
n.a. |
3.0 |
n.a. |
n.a. |
n.a. |
|
As |
µg/g |
66.2 |
4.8 H |
2.73 |
1.15 |
1.16h |
24.4 |
0.41 |
<0.2 |
4.40 |
9.45 |
|
Se |
µg/g |
4.0 |
<1.5 |
<0.5 |
<1. |
(0.06) |
(3.) |
<0.2 |
<0.5 |
<0.5 |
<0.7 |
|
Br |
µg/g |
0.49 |
1.5 |
<0.5 |
(0.24) |
0.50 |
1.27 |
<0.2 |
<0.2 |
2.34 |
1.14 |
|
Rb |
µg/g |
79.0 |
113.7 |
62.1 |
21.2 |
11.6 |
4.4 |
522. |
104.4 |
127. |
189. |
|
Sr |
µg/g |
393. |
720. |
307. |
206. |
269. |
134. |
62. |
431. |
67. |
82. |
|
Y |
µg/g |
[10.3] |
[48.] |
[26.] |
[22.] |
[4.1] |
[78.] |
[1.16] |
[1.53] |
[41.] |
[41.] |
|
Zr |
µg/g |
45. |
1270. |
131. |
93. |
29. |
2670. |
<15. |
(7.) |
287. |
146. |
|
Ag |
µg/g |
(0.25) |
n.a. |
<2. |
n.a. |
n.a. |
n.a. |
3.2 H |
n.a. |
n.a. |
n.a. |
|
Cd |
µg/g |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
n.a. |
|
Sb |
µg/g |
3.29h |
1.56 |
1.43 H |
0.75h |
0.155 |
1.89 |
0.168 |
0.030 |
<1.5>H |
0.708 |
|
Cs |
µg/g |
5.19 |
1.517 |
2.88 |
0.89 |
0.545 |
0.15 |
9.45 |
0.481 |
5.13 |
9.68 |
|
Ba |
µg/g |
270. |
571. |
729. |
163. |
78. |
77. |
120. |
2460. |
890. |
439. |
|
La |
µg/g |
18.4 |
151.1 |
12.3 |
10.60 |
4.51 |
75.0 |
0.47h |
2.64h |
30.1 |
49.8 |
|
Ce |
µg/g |
34.4 |
264. |
28.2 |
22.8 |
7.27 |
249. |
0.51h |
4.3h |
61.8 |
103.2 |
|
Pr |
µg/g |
[3.7] |
[24.] |
[3.7] |
[2.8] |
[1.0] |
n.a. |
n.a. |
[0.50] |
[6.8] |
[11.5] |
|
Nd |
µg/g |
13.8 |
77. |
16.4 |
12.2 |
4.3 |
31. |
<1. |
2.1 |
26.0 |
44. |
|
Sm |
µg/g |
2.60 |
12.3 |
4.18 |
3.33 |
0.815 |
5.73 |
0.092 h |
0.48h |
5.79 |
9.12 |
|
Eu |
µg/g |
0.466 |
3.42 |
0.992 |
1.087 |
0.156 |
0.866 |
0.575 |
0.781 |
0.769 |
1.78 |
|
Gd |
µg/g |
[1.9] |
[9.1] |
[4.3] |
[3.5] |
[0.70] |
[5.7] |
[0.13] |
[0.43] |
[5.3] |
[7.4] |
|
Tb |
µg/g |
0.297 |
1.425 |
0.711 |
0.605 |
0.116 |
1.21 |
0.025 H |
0.064h |
0.961 |
1.193 |
|
Dy |
µg/g |
[1.8] |
[8.5] |
[4.4] |
[3.8] |
[0.71] |
[9.2] |
[0.17] |
[0.34] |
[6.3] |
[7.2] |
|
Ho |
µg/g |
[0.38] |
[1.8] |
[0.95] |
[0.82] |
[0.15] |
[2.4] |
[0.041] |
[0.061] |
[1.5] |
[1.5] |
|
Er |
µg/g |
[1.0] |
[4.8] |
[2.6] |
[2.2] |
[0.41] |
[8.0] |
[0.12] |
[0.14] |
[4.2] |
[4.0] |
|
Tm |
µg/g |
[0.15] |
[0.68] |
[0.37] |
[0.32] |
[0.060] |
[1.39] |
[0.019] |
[0.017] |
[0.65] |
[0.58] |
|
Yb |
µg/g |
0.966 |
4.32 |
2.41 |
2.05 |
0.388 |
10.4 |
0.13 H |